文献类型：期刊文献

英文题名：A single chemosensor for bimetal Cu(II) and Zn(II) in aqueous medium

作者：Liao, Zhuang[1];Wang, Dan[1];Zheng, Jian-Quan[2];Tan, Hong-Wei[1];Zheng, Xiang-Jun[1];Jin, Lin-Pei[1]

第一作者：Liao, Zhuang

通讯作者：Zheng, XJ[1]

机构：[1]Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China;[2]Beijing Union Univ, Beijing Key Lab Bioact Subst & Funct Foods, Beijing 100191, Peoples R China

第一机构：Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China

通讯机构：[1]corresponding author), Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China.

年份：2016

卷号：6

期号：40

起止页码：33798-33803

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20161802317720);Scopus(收录号：2-s2.0-84964501724);WOS:【SCI-EXPANDED(收录号:WOS:000374045000067)】；

语种：英文

外文关键词：Binding sites - Single crystals - Synthesis (chemical) - Zinc compounds

摘要：A new quinazoline derivative 6-(4-diethylamino)phenol-2-yl-(5,6-dihydrobenzimidazo[1,2-c])-quinazoline (HL) and the two metal Schiff-base complexes [(CuLCl)-Cl-1]center dot CH3OH (1) and [ZnL1(Ac)]center dot 0.5CH(3)CH(OH)CH3 (2) (HL1 = 4-{[2-(1H-benzoimidazol-2-yl)-phenyl imino]-methyl}-benzene-1-diethylamino-3-ol) were synthesized and characterized by single-crystal X-ray diffraction. HL is highly selective and sensitive to Cu(II) and Zn(II) ions in aqueous medium with a detection limit of 2.13 x 10(-6) and 7.19 x 10(-7) M for Cu2+ and Zn2+, respectively. HL can act as a "turn-off" sensor for Cu(II) with the excitation wavelength of 356 nm and a "turn-on" sensor for Zn(II) when excited at 416 nm. The Job plots, fluorescence and UV-vis titrations, H-1 NMR as well as ESI data show that the binding stoichiometry of Cu(II)/Zn(II) with HL is 1 : 1. The binding sites of HL with Cu(II)/Zn(II) are two nitrogen atoms and one oxygen atom, forming Cu(II)-L-1 and Zn(II)-L-1 complexes. This agrees with the crystal structures of 1 and 2.