文献类型：期刊文献

英文题名：A novel gas sensor of formaldehyde and ammonia based on cross sensitivity of cataluminescence on nano-Ti3SnLa2O11

作者：Fan, Huizhen[1];Cheng, Yanling[1,2];Gu, Chunxiu[1,2];Zhou, Kaowen[1,2]

第一作者：Fan, Huizhen

通讯作者：Zhou, K[1]

机构：[1]Beijing Union Univ, Biochem Engn Coll, Beijing 100023, Peoples R China;[2]Beijing Key Lab Biomass Waste Resource Utilizat, Beijing 100023, Peoples R China

第一机构：北京联合大学生物化学工程学院

通讯机构：[1]corresponding author), 18 Fatouxilisanqu, Beijing 100023, Peoples R China.

年份：2016

卷号：223

起止页码：921-926

外文期刊名：SENSORS AND ACTUATORS B-CHEMICAL

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000366458700120)】；

基金：This work was supported by Beijing Natural Science Foundation (Grant No. 2152013), Key Projects of Science and Technology Plan from Beijing Municipal Education Commission of China (KZ201311417038), State 863 Projects (2014AA022002), National International Cooperation Projects (2014DFA61040) and Research Base Projects (Z141109004414002).

语种：英文

外文关键词：Formaldehyde; Ammonia; Cross sensitivity; Algebraic sum rule; Gas sensor

摘要：A credible method based on cross sensitivity of cataluminescence (CTL) on nano-Ti3SnLa2O11 was proposed for simultaneously determining formaldehyde and ammonia in air. The experimental conditions satisfying the algebraic sum rule of the CTL intensities of formaldehyde and ammonia were ascertained. They are two analysis wavelengths of 575 nm and 675 nm, the surface temperature of sensing materials of 350 degrees C and the flow rate of air carrier of 300 mL/min. The limits of detection of this method were 0.06 mg/m(3) for formaldehyde and 0.14 mg/m(3) for ammonia. The linear ranges of CTL intensity versus analyte concentration were 0.17-51.5 mg/m(3) for formaldehyde and 0.31-59.6 mg/m(3) for ammonia. The recoveries of 10 testing standard samples by this method were 97.3-102.7% for formaldehyde and 97.6-102.4% for ammonia. Common coexistence matters, such as acetaldehyde, methylamine, benzene, toluene, ethylbenzene, ethanol, sulfur dioxide and carbon dioxide, did not disturb the determination. The relative deviation (RD) of CTL signals of continuous 150 h detection for gaseous mixture containing formaldehyde and ammonia was less than 3%, which demonstrated the longevity and steady performance of nano-Ti3SnLa2O11 to formaldehyde and ammonia. (C) 2015 Published by Elsevier B.V.