文献类型：期刊文献

英文题名：Structural and Hirshfeld Surface Analyses of a Novel Hetero-Tetranuclear Cu-II-Na-I Bis(Salamo)-Based Coordination Compound

作者：Sun, Ya-Xuan[1];Liu, Ling-Zhi[2];Wang, Fei[2];Shang, Xiao-Ya[1];Chen, Le[2];Dong, Wen-Kui[2]

第一作者：孙雅煊

通讯作者：Shang, XY[1];Dong, WK[2]

机构：[1]Beijing Union Univ, Beijing Key Lab Bioact Subst & Funct Foods, Beijing 100191, Peoples R China;[2]Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China

第一机构：北京联合大学应用文理学院|北京联合大学生物化学工程学院

通讯机构：[1]corresponding author), Beijing Union Univ, Beijing Key Lab Bioact Subst & Funct Foods, Beijing 100191, Peoples R China;[2]corresponding author), Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China.|[114172]北京联合大学应用文理学院;[11417]北京联合大学;[1141726]北京联合大学生物化学工程学院;

年份：2018

卷号：8

期号：5

外文期刊名：CRYSTALS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000435192500046)】；

基金：The work was financially supported by the National Natural Science Foundation of China (21761018), the Scientific Research Project from Facing Characteristic Discipline of Beijing Union University (KYDE40201703), the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706) and Beijing Key Laboratory of Bioactive Substances and Functional Foods, Beijing Union University (12213991724010239), which is gratefully acknowledged.

语种：英文

外文关键词：bis(Salamo)-type ligand; hetero-tetranuclear; Cu-II-Na-I coordination compound; crystal structure; hirshfeld surface analysis

摘要：The newly designed butterfly-shaped hetero-tetranuclear CuII-NaI coordination compound, [Cu-3(HL)(2)Na]center dot Pic (Pic(-) is abbreviation of picrate) (1) which is derived from a naphthalenediol-based bis(Salamo)-type chelating ligand H4L have been synthesized and characterized by elemental analyses, UV-vis spectra, IR spectra analysis, and Hirshfeld surface analysis. X-ray crystallographic analyses revealed that the coordination compound 1 is a novel hetero-tetranuclear Cu-II-Na-I bis(Salamo)-type coordination compound and it differs from heterotrinuclear Cu-II-Na-I bis(Salamo)-type coordination compound reported earlier. The Cu1 and Cu3 atoms are tetra-coordinated with geometries of distorted square pyramid, while Cu2 atom are hexa-coordinated with the geometry of a distorted octahedron. The Na-I atom is octa-coordinated with the geometry of a distorted hexagonal bipyramid. Furthermore, the supramolecular structure and Hirshfeld surface analyses have been discussed in detail.