文献类型：期刊文献

中文题名：固相萃取-高效液相色谱法测定水中BPA、NP和OP含量

英文题名：Simultaneous Determination of Nonylphenol,Octylphenol and Bisphenol-A in Water by Solid-Phase Extraction High Performance Liquid Chromatography

作者：张琦[1];董慧茹[1]

第一作者：张琦

机构：[1]北京联合大学旅游学院酒店与餐饮管理系

第一机构：北京联合大学旅游学院餐饮管理系

年份：2009

卷号：25

期号：2

起止页码：157-160

中文期刊名：分析科学学报

外文期刊名：Journal of Analytical Science

收录：CSTPCD;;北大核心:【北大核心2008】；CSCD:【CSCD2011_2012】；

基金：中国石化集团公司研究项目(No.J306002)

语种：中文

中文关键词：固相萃取;高效液相色谱;壬基酚;辛基酚;双酚A

外文关键词：High performance liquid chromatography; Nonylphenol; Octylphenol; Bisphenol-A; Solid- phase extraction

摘要：采用国产新型D4020大孔吸附树脂自制固相萃取柱，研究了柱长、上样速度、样品溶液的PH、盐浓度等因素对壬基酚、辛基酚和双酚A吸附率的影响，确定了最佳固相萃取条件，建立了固相萃取-高效液相色谱测定水中痕量壬基酚、辛基酚和双酚A的分析方法。该法双酚A、壬基酚和辛基酚的检出限分别为0．432μg／L、0．998μg／L和1．336μg／L，回收率为91％～96％，相对标准偏差（RSD）为1．5％～5．6％。方法简便快速、成本低廉，灵敏度高，准确度好，用于实际水样分析，取得满意结果。
A method for the determination of nonylphenol, octylphenol and bisphenol-A in water has been established by high performance liquid chromatography （HPLC） with solid-phase extraction （SPE）. In this study, D4020 macro-reticulate resin was used for the first time as an absorbent for alkylphenol compounds in water. Through the choise of SPE conditions which include the pH value of water sample, load speed, elution speed, etc, the optimum inspection conditions were got. The results showed that the recoveries of different concentrations were between 91% and 96%, the RSD was generally below 5. 6G, the detection limits were 0. 432 μg/L for bisphenol-A, 0. 998 μg/L for nonylphenol and 1. 336 μg/L for octylphenol, respectively. The determination results of water samples were satisfactory. The method is simple, fast and applicable for routine analysis.