文献类型：期刊文献

英文题名：Practical separation performance evaluation of coal mine methane upgrading with carbon molecular sieves

作者：Yang, Xiong[1,2];Li, Ziyi[1,2];Zhang, Chuanzhao[3];Wang, Haoyu[3];Zhang, Erlin[1];Xing, Yi[1,2];Xiao, Penny[5];Yang, Ralph T.[4];Liu, Yingshu[1,2];Webley, Paul A.[5]

第一作者：Yang, Xiong

通讯作者：Li, ZY[1];Xing, Y[1];Xing, Y[2]

机构：[1]Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China;[2]Beijing Higher Inst Engn Res Ctr Energy Conservat, Beijing 100083, Peoples R China;[3]Beijing Union Univ, Coll Biochem Engn, Beijing 100023, Peoples R China;[4]Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA;[5]Univ Melbourne, Dept Chem Engn, Melbourne, Vic 3010, Australia

第一机构：Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China

通讯机构：[1]corresponding author), Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China;[2]corresponding author), Beijing Higher Inst Engn Res Ctr Energy Conservat, Beijing 100083, Peoples R China.

年份：2019

卷号：367

起止页码：295-303

外文期刊名：CHEMICAL ENGINEERING JOURNAL

收录：;EI(收录号：20190906565189);Scopus(收录号：2-s2.0-85062058948);WOS:【SCI-EXPANDED(收录号:WOS:000461380400030)】；

基金：This work was supported by the National Natural Science Foundation of China (Nos. 51604016, 21676025), Beijing Natural Science Foundation (Nos. 8182019, 8174064), the National Key R&D Program of China (No. 2017YFC0210302, 2017YFC0210303), the National Postdoctoral Program for Innovative Talents (No. BX201700029), the China Postdoctoral Science Foundation (No. 2018M630075), and the Fundamental Research Funds for the Central Universities (No. FRF-TP-17-063A1, FRF-BD-18-015A).

语种：英文

外文关键词：coal mine methane (CMM); Methane upgrading; Carbon molecular sieve (CMS); Kinetic separation; Pressure swing adsorption (PSA)

摘要：Upgrading coal mine methane (CMM) with adsorption method is an effective way to enhance the energy utilizing efficiency and reduce greenhouse gas emissions. In this work, adsorption equilibrium and kinetics of CH4, N-2 and O-2, as typical components in CMM, on three carbon molecular sieves (CMSs) and the corresponding separation performances were studied. The equilibrium and kinetic selectivity were obtained from adsorption isotherms fitted with the Langmuir model and uptake curves fitted with the micropore-diffusion model, respectively. O-2 with the highest diffusion time constant among three gases suggests the advantage of CMS-based kinetic separation in deoxygenation of CMM and the critical role that N-2/CH4 kinetic separation plays in CH4 enrichment. CMS-1 with the highest microporosity has the largest adsorption capacities, and CMS-3 with a proper average pore size has the greatest N-2/CH4 kinetic selectivity. The actual separation performances shown by CH4/N-2/O-2 breakthrough curves according to the principle for practical CMM upgrading processes exhibit the order of CMS1 > CMS-3 > CMS-2 which is inconsistent with that of the conventional N-2/CH4 selectivity highly due to the underestimation of effects of N-2 equilibrium adsorption relative to N-2 kinetic selection without covering specific adsorption range corresponding to practical working capacity region. A modified selectivity with consideration of actual N-2 amount adsorbed was therefore developed, showing the correct performance order and the potential to be used as a practical adsorbent selection parameter. An advanced CMS materials design with proper existence of microporosity would benefit practical CMM upgrading in terms of reaching an optimal balance between adsorption equilibrium and kinetics.