文献类型：期刊文献

英文题名：Current material design strategies on the copper chalcogenide cathodes for rechargeable magnesium batteries: a review

作者：Liu, Xin[1];Zhang, Qianwei[1];Du, Changliang[1];Du, Xiao[2];Zhu, Youqi[1];Cao, Chuanbao[1]

第一作者：Liu, Xin

通讯作者：Zhu, YQ[1];Cao, CB[1]

机构：[1]Beijing Inst Technol, Res Ctr Mat Sci, Beijing Key Lab Construct Tailorable Adv Funct Mat, Beijing 100081, Peoples R China;[2]Beijing Union Univ, Smart City Coll, Beijing 100101, Peoples R China

第一机构：Beijing Inst Technol, Res Ctr Mat Sci, Beijing Key Lab Construct Tailorable Adv Funct Mat, Beijing 100081, Peoples R China

通讯机构：[1]corresponding author), Beijing Inst Technol, Res Ctr Mat Sci, Beijing Key Lab Construct Tailorable Adv Funct Mat, Beijing 100081, Peoples R China.

年份：2023

外文期刊名：MATERIALS CHEMISTRY FRONTIERS

收录：;EI(收录号：20232814376025);Scopus(收录号：2-s2.0-85164325969);WOS:【SCI-EXPANDED(收录号:WOS:001016452100001)】；

基金：We acknowledge the financial support from the National Natural Science Foundation of China (21371023 and 52173273) and the Fundamental Research Funds for the Central Universities (2022CX11013).

语种：英文

摘要：Rechargeable magnesium batteries (RMBs) are proposed to be conceivable rivals to replace lithium-ion batteries as next-generation energy storage devices. Nevertheless, the applications of RMBs are still hindered by the limited choice of high-performance cathode materials. Due to the impressively high theoretical capacity, copper chalcogenides have gained notable attention as a prospective electrode material. However, the implementation of copper chalcogenides with high energy density and rapid kinetics of Mg2+ insertion/extraction is in serious demand. In this review, the organized summary of all reaction mechanisms of copper chalcogenide cathodes for ion storage (intercalation, conversion and displacement type) is presented at first. Especially, five design and modification strategies for copper chalcogenide cathodes from macroscopic and microscopic aspects are highlighted, focusing on the size, morphology and structure, material composite, crystal structure and atomic substitution. This review ultimately offers practical recommendations and potential directions for the future development of copper chalcogenide cathodes for magnesium battery systems.